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2 edition of Liquid phase fluorination of some adamantane derivatives found in the catalog.

Liquid phase fluorination of some adamantane derivatives

R. A. Du Boisson

Liquid phase fluorination of some adamantane derivatives

by R. A. Du Boisson

  • 321 Want to read
  • 4 Currently reading

Published by UMIST in Manchester .
Written in English


Edition Notes

StatementSupervised by: Haszeldine, R.N..
ContributionsHaszeldine, R. N., Supervisor., Chemistry.
ID Numbers
Open LibraryOL19657542M

Hexamethylenetetramine or methenamine, also known as hexamine or urotropin, is a heterocyclic organic compound with the formula (CH 2) 6 N white crystalline compound is highly soluble in water and polar organic solvents. It has a cage-like structure similar to is useful in the synthesis of other chemical compounds, e.g., plastics, pharmaceuticals, rubber g point: °C ( °F; K) (sublimes). Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v estimate) = Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v): Boiling Pt (deg C): (Adapted Stein & Brown method) Melting Pt (deg C): (Mean or Weighted MP) VP(mm Hg,25 deg C): (Modified Grain .

Adamantane is a colorless, crystalline chemical compound with a camphor-like a formula C 10 H 16, it is a cycloalkane and also the simplest tane molecules consist of three cyclohexane rings arranged in the "armchair" configuration. It is unique in that it is both rigid and virtually stress-free. Adamantane is the most stable among all the isomers with formula C 10 H.   (g) continuing said fluorination until substantial perfluorination has been completed. 2. The liquid phase fluorination method as in claim 1, wherein the fluorination is carried out at ° to +25° C. 3. The liquid phase fluorination method as in claim 1, .

Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v estimate) = Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v): Boiling Pt (deg C): (Adapted Stein & Brown method) Melting Pt (deg C): (Mean or Weighted MP) VP(mm Hg,25 deg C): (Mean VP of Antoine . Derivatives in which the amino group was attached to ethyl or propyl side chains at position 3 of the adamantane ring were also effective at inhibiting parasite growth (see data for compounds 2/15, 2/, 2/23, and 2/, Table Table1). 1). These activities, however, could also be dramatically affected by other substitutions on the adamantane by:


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Liquid phase fluorination of some adamantane derivatives by R. A. Du Boisson Download PDF EPUB FB2

A facile synthesis for 1-fluoro(trifluoromethyl)adamantane, based on fluorination of 3-hydroxyadamantanecarboxylic acid, was developed. Its synthetic potentialities for preparation of (trifluoromethyl)adamantane derivatives containing diverse functional groups (acids, amines, etc.) in a bridgehead position, were : Yevheniia Y.

Zhyhadlo, Alexander V. Gaidai, Igor A. Levandovskiy, Andriy V. Bezdudny, Yuliya V. Rass. The Lipophilic Bullet Hits the Targets: Medicinal Chemistry of Adamantane Derivatives Lukas Wanka, Khalid Iqbal, and Peter R.

Schreiner Chemical Reviews (5), Cited by: The formation of halogenated succinates by liquid-phase direct fluorination with elemental fluorine. Journal of Fluorine Chemistry67 (3), DOI: /(93) by: * Corresponding author. the liquid-phase fluorination occurs heterogeneously at the gas-liquid interface, with consequent serious damage caused by fluorine to the reaction environment.

Greater solubilization of fluorine could thus ensure the possibility of Cited by: On the mechanism of liquid phase halogenation of adamantane derivatives Author links open overlay panel A.G.

Yurchenco N.I. Kulik V.P. Kuchar V.M. Djakovskaja V.F. Baklan Show moreCited by: 7. Oxidative Functionalization of Adamantane and Some of Its Derivatives in Solution. The Journal of Organic Chemistry61 (4), DOI: /joy. Timothy L. Macdonald, N. Narasimhan, Leo T. Burka. Chemical and biological oxidation of by: Chromatographic elution data for monocyclic, aromatic and polycyclic halogeno derivatives of the adamantane type have been measured on silica, using n-pentane as mobile phase.

The water content in the recycled mobile phase was controlled by an integral moisture control system containing coarse silica with1 and 2% water, by: It was found that ionic liquid containing imidazolium and their counter anions8, 8(a), 8(b), 8(c), 8(d), 8(e) as alternative reaction media can enhance the reactivity of alkali metal fluorides in the nucleophilic fluorination remarkably.9, 9(a), 9(b), 9(c) In particular, polystyrene-based polymer-supported ionic liquids (PSILs) have shown still Cited by:   Ionic Liquid-Mediated Hydrofluorination of o-Azaxylylenes Derived from 3-Bromooxindoles.

Organic Letters19 (10), DOI: /t.7b Kelan Liu, Yiseng Hu, Zejun Xu, and Meizhen by: Some alkyl derivatives of adamantane have been used as a working fluid in hydraulic systems. Adamantane-based polymers might find application for coatings of touchscreens, and there are prospects for using adamantane and its homologues in nanotechnology.

For example, the soft cage-like structure of adamantane solid allow incorporation of guest molecules, which can be released inside Chemical formula: C₁₀H₁₆.

Energy Properties of Adamantane Derivatives were evaluated for some compounds by taking into account the literature data on the condensed phase enthalpies of formation and the ΔfHo (g. James L. Adcock's 70 research works with citations and reads, including: ChemInform Abstract: X-Ray Crystal Structure of the First Quaternary 1-Bicyclo() pentane Salt.

The Shortest. Liquid phase halogenation of hexachlorobenzene by chlorine trifluoride appears to proceed by a series of additions and vinylic and allylic substitutions, until all of the hexachlorobenzene is.

Bayat, Z.; Abad, M.F.Y., Quantitative structure-property relationship (QSPR) study of Kovats retention indices of some of adamantane derivatives by the genetic algorithm amd nultiply linear regression (GA-MLR) method, Petroleum Coal,53, 2, Adamantane is a colorless, crystalline chemical compound with a camphor-like a formula C 10 H 16, it is a cycloalkane and also the simplest tane molecules consist of four connected cyclohexane rings arranged in the "armchair" configuration.

It is unique in that it is both rigid and virtually stress-free. Adamantane is the most stable among all the isomers with CAS number: A new synthetic procedure for the preparation of perfluorinated ketones from nonfiuorinated sec-alcohols was developed.

A key step in the synthetic route was a liquid-phase direct fluorination. This project is supported by the Canadian Institutes of Health Research (award #), Alberta Innovates - Health Solutions, and by The Metabolomics Innovation Centre (TMIC), a nationally-funded research and core facility that supports a wide range of cutting-edge metabolomic is funded by Genome Alberta, Genome British Columbia, and Genome Canada, a not-for-profit organization.

In fact, in the liquid-phase direct fluorination process, the reactant is injected at a very slow constant rate into an inert fluorocarbon solvent saturated by fluorine. It is pointed out to be very important that a large excess of F 2 relative to hydrogen atoms to be replaced in a substrate should be maintained.

This method is, however, only Cited by:   The liquid‐phase preparation of copper, either as freestanding submicrometer‐thin foil or supported on a substrate, is presented by M. Niederberger et al. in their Communication on page ff. A solution of copper acetylacetonate initially forms a mirror on.

Alexander E Sorochinsky. [Reverse phase high performance liquid chromatography in the synthesis of leukotrienes A4 and C4] FLUORO DERIVATIVES OF ADAMANTANE. FLUORINATION OF 2. A Preparative Gas-Solid-Phase Synthesis of Acetyl Hypofluorite.

Synthetic Communications14 (1), DOI: / O. LERMAN, S. ROZEN. ChemInform Abstract: ACETYL HYPOFLUORITE, A NEW MODERATING CARRIER OF ELEMENTAL FLUORINE AND ITS USE IN FLUORINATION OF 1,3-DICARBONYL DERIVATIVES.The discovery of adamantane in petroleum in launched a new field of chemistry dedicated to studying the synthesis and properties of polyhedral organic compounds.

Adamantane derivatives have found practical application as drugs, polymeric materials, and .アダマンタン (adamantane) は、10個の炭素がダイヤモンドの構造と同様に配置されている、かご型の分子である。 化学式はC 10 H 16 、分子量は。 融点は °C 。 CAS登録番号は []。名称はダイヤモンドに相当するギリシャ語の "adamas" から名づけられたものである。モル質量: g mol−1.